Lasers Intro
Absorption #
Stimulated #
atom: E₁→E₂ (E₂>E₁) Rate ∝
- number of atoms in ground state
- density of photons
Emission #
Spontaneous #
De-excitation: E₂→E₁ Rate ∝
- number of atoms in excited state
Stimulated #
Photon of energy E₁-E₂=hν interacts with atom in E₂,
De-excitation takes place: E₂→E₁, two photons are released
Rate ∝
- number of atoms in excited state
- density of photons
Difference #
Spontaneous | Stimulated |
---|---|
Postulated by Bohr | Postulated by Einstein |
No extra photons are needed | Additional photons are required |
1 photon is emitted | 2 photons are emitted |
Less directionality | Highly directional |
Greater angular spread/divergence | Divergence is extremely small ($10^{-6}\rightarrow10^{-5}$) |
Poly-chromatic | Highly monochromatic |
Low intensity | High intensity |
Incoherent | Highly coherent |
eg: light from sodium or mercury lamp | eg: light from laser source |
Coherence #
It is of two types
- Temporal coherence: A point on a wave is coherent with another point on the same wave
- Spatial coherence: A point on a wave is coherent with a point on another wave.
Population Inversion #
When N₂ atoms in E₂ > N₁ atoms in E₁ where E₂>E₁ Usually more atoms stay in lower energy levels so if the inverse happens, it’s called a population inversion.
Distribution #
$$ N_i=N_0\cdot e^\left(-\frac{E_i}{kT}\right)$$
Einstein coefficients #
N₁,N₂ atoms in E₁,E₂ energy levels number of photons per unit volume: n Energy density of photons p(v) = nhv At equilibrium upward transition = downward transition
Upward Transition #
- Stimulated absorption rate = $B_{12}N₁p(v)$
- $B_{12}$: Einstein coefficient of stimulated absorption
Downward Transition #
- Stimulated emission rate = $B_{21}N_2p(v)$
- $B_{21}$: Einstein coefficient of stimulated emission.
- Spontaneous emission rate = $A_{21}N_2$
- $A_{21}$: Einstein coefficient of spontaneous emission.
Deriving p(v) #
$$ \begin{align} B_{12}N₁p(v)=B_{21}N_2p(v)+A_{21}N_2\\ p(v)=\frac{A_{21}N_2}{B_{12}N_1-B_{21}N_2}\\ Dividing\\ numerator\\ and\\ denominator\\ by\\ B_{21}N_2\\ p(v)=\frac{\frac{A_{21}N_2}{B_{21}N_2}}{\frac{B_{12}}{B_{21}}\cdot e^{-\frac{E_1-E_2}{kT}}-1} \end{align} $$ From Plank’s Hypothesis we know that u(v) or p(v)=$\frac{8\pi v}{c^3}\cdot \frac{hv}{e^{\frac{hv}{kT}}-1}=\frac{8\pi hv^3/c^3}{e^{\frac{E_2-E_1}{kT}}-1}$ So, $\frac{B_{12}}{B_{21}}=1$ and $\frac{A_{21}}{B_{21}}=8\pi hv^3/c^3$